Castor oil is unique in that it is a triacylglycerol (TAG) oil in which
nearly 90% of the fatty acids are the unusual fatty acid, Ricinoleic
acid (18:1-OH).
Hydroxy fatty acids are only
rarely found in the plant kingdom. A small number of species are known
to produce ricinoleic acid but none make an oil of the incredible acyl
purity of castor oil.
Biochemical studies have revealed
that ricinoleic acid is produced in castor by the direct hydroxylation
of the common fatty acid, oleic acid (18:1).
The hydroxylation reaction
is catalysed by a single, highly efficient enzyme, the fatty acid hydroxylase.
This enzyme has been cloned
and expressed in genetically engineered plants to produce novel seed
oils containing ricinoleic acid.
Linnaeus has exclusive rights
to this enzyme and the utilization of fatty acid hydroxylases in transgenic
plants to produce seed oils containing hydroxy fatty acids.